東北大学 大学院工学研究科 バイオ工学専攻

2021

"Mechanistic Consideration for the Selective Inclusion of Disubstituted Benzene Isomers with p-tert-Butylcalix[4]arene Crystals"
Matsumoto, T.; Sasaki, T.; Tonosaki, A.; Morohashi, N.; Hattori, T.
Cryst. Growth Des. 2021, in press.

"Inclusion of Amine Isomers with Open-Chain Hosts Having a Partial Structure of p-tert-Butylthiacalixarene"
Miyoshi, I.; Sonehara, H.; Ogihara, J.; Matsumoto, T.; Morohashi, N.; Hattori, T.
J. Org. Chem. 2021, 86, 7046.

"Synthesis of an azadioxa-planar triphenylborane and investigation of its structural and photophysical properties"
Kitamoto, Y.; Oda, K.; Ogino, k.; Hiyama, K.; Kita, H.; Hattori, T.; Oi, S.
Chem. Commun. 2021, 57, 2297.
[Highlighted in SYNFACTS 2021, 17, 0508.]

2020

"Extraction of Pd(II) and Pt(II) from aqueous hydrochloric acid with 1,3-diaminocalix[4]arene: switching of the extraction selectivity by using different extraction modes"
Morohashi, N.; Kurusu, Y.; Akasaka K.; Hattori T.
RSC Adv 2020, 10, 35473.

"Enantioselective inclusion of pyrene-1-sulfonate salts of α-amino acids with crystals of α-cyclodextrin"
Miyoshi, I.; Kitamoto, Y.; Maeda, T.; Morohashi, N.; Hattori, T.
Tetrahedron 2020, 76, 131100.

2019

"Inclusion of Alkanes with a Crystal Consisting of Exocavity Complexes of p‑tert-Butylthiacalix[4]arene with Diethylamine: Extension of Guest Scope by Changing the Structure of Inclusion Crystals"
Morohashi, N.; Miyoshi, I.; Sasaki, T.; Nakaji, Y.; Nakayama, H.; Hattori, T.
Cryst. Growth Des. 2019, 19, 7022.

"Acylation of Alkenes with the Aid of AlCl₃ and 2,6-Dibromopyridine"
Tanaka, S.; Kunisawa, T.; Yoshii, Y.; Hattori, T.
Org. Lett. 2019, 21, 8509.

"Selective Extraction of Zr(IV) over Hf(IV) from Aqueous Hydrochloric Acid with p-tert-Butylcalix[4]arenediphosphonic Acid"
Morohashi, N.; Kato, Y.; Sumida, S.; Kurusu, S.; Hattori, T.
Bull. Chem. Soc. Jpn. 2019, 92, 967.

2018

"二酸化炭素と水素からギ酸をつくる"
田中信也
化学 2018, 73(9), 62.

"二酸化炭素によるアルケンのカルボキシル化"
田中信也
化学と工業 2018, 71, 230.

"カリックスアレーンの結晶による高選択的な有機分子包接現象"
諸橋直弥
超分子研究会アニュアルレビュー 2018, 38, 12.

"Electrophilic Borylation of Terminal Alkenes with BBr₃/2,6-Disubstituted Pyridines"
Tanaka, S.; Saito, Y.; Yamamoto, T.; Hattori, T
Org. Lett. 2018, 20, 1828.

"Design and Synthesis of Open-Chain Hosts Having a Partial Structure of p-tert-Butylthiacalixarene"
Morohashi, N.; Nanbu, K.; Sonehara, H.; Ogihara, J.; Shimazaki, T.; Hattori, T.
J. Org. Chem. 2018, 83, 2235.

"Recovery of host crystals from inclusion crystals of p-tert-butylcalix[4]arene and p-tert-butylthiacalix[4]arene by the treatment with a solvent and/or supercritical CO₂"
Morohashi, N.; Ebata, K.; Hattori, T.
J. Inclusion Phenom. Macrocyclic Chem. 2018, 90, 279.

"Selective guest inclusion by crystals of calixarenes: potential for application as separation materials" (Selected for SHGSC Japan Award of Excellence 2017)
Morohashi, N.; Hattori, T.
J. Inclusion Phenom. Macrocyclic Chem. 2018, 90, 261.

"1,3-Bis(pyren-1-yliminomethyl)calix[4]arene as a selective fluorescent turn-on sensor for mercury(II) ion"
Tanaka, S.; Hirasawa, K.; Watanabe, K.; Hattori, T.
Supramol. Chem. 2018, 30, 179.

2017

"Competitive Inclusion of Disubstituted Benzenes Regioisomers with Crystals of p-tert-Butylcalix[4]arene"
Morohashi, N.; Tonosaki, A.; Kitagawa, T.; Sasaki, T.; Ebata, K.; Hattori, T.
Cryst. Growth Des. 2017, 17, 5038.

"Selective Extraction of Pd(II) by p-tert-Butylcalix[4]arenedicarboxylic Acid"
Morohashi, N.; Iijima, S.; Akasaka, K.; Hattori, T.
New J. Chem. 2017, 49, 2231.

"AlBr₃-Mediated Tandem Cyclization–Carboxylation of Allenylbenzenes with CO₂ in the Presence of Pyridines"
Tanaka, S.; Chiba, M.; Saito, Y.; Yamamoto, T.; Hattori, T.
Bull. Chem. Soc. Jpn. 2017, 90, 419.

"Competitive Inclusion of Carboxylic Acids with a Metastable Crystal Polymorph of p-tert-Butylthiacalix[4]arene"
Morohashi, N.; Ebata, K.; Nakayama, H.; Noji, S.; Hattori, T.
Cryst. Growth Des. 2017, 17, 891.

2016

"Inclusion of methylamines with the crystal of p-tert-butylthiacalix[4]arene: inclusion selectivity and its switching by solvent polarity"
Morohashi, N.; Shibata, O.; Miyoshi, I.; Kitamoto, Y.; Ebata, K.; Nakayama, H.; Hattori, T.
Cryst. Growth Des. 2016, 16, 4671.

"EtAlCl₂/2,6-Disubstituted Pyridine-Mediated Carboxylation of Alkenes with Carbon Dioxide"
Tanaka, S.; Watanabe, K.; Tanaka, Y.; Hattori, T.
Org. Lett. 2016, 18, 2576.
[Highlighted in SYNFACTS 2016, 12, 0851 and Org. Process Res. Dev. 2016, 20, 1691.]

"Pd(II) complexes ligated by 1,3-bis(diphenylphosphino)calix[4]arene: Preparation, X-ray structures, and catalyses"
Hirasawa, K.; Tanaka, S.; Horiuchi, T.; Kobayashi, T.; Sato, T.; Morohashi, N.; Hattori, T.
Organometallics 2016, 35, 420.

"Me₂AlCl-mediated carboxylation, ethoxycarbonylation, and carbamoylation of indoles"
Nemoto, K.; Tanaka, S.; Konno, M.; Onozawa, S.; Chiba, M.; Tanaka, Y.; Sasaki, Y.; Okubo, R.; Hattori, T.
Tetrahedron 2016, 72, 734.

"硫黄の特性を利用したチアカリックスアレーンの分子設計と機能"
諸橋直弥；服部徹太郎
硫酸と工業 2016, 69, 153.

2015

"Comparison of inclusion properties between p-tert-butylcalix[4]arene and p-tert-butylthiacalix[4]arene towards primary alcohols in crystals"
Morohashi, N.; Nanbu, K.; Tonosaki, A.; Noji, S.; Hattori, T.
CrystEngComm 2015, 17, 4799.

"Lewis Acid-Mediated β-Selective Hydrocarboxylation of α-,α-Diaryl- and α-Arylalkenes with R₃SiH and CO₂"
Tanaka, S.; Tanaka, Y.; Chiba, M.; Hattori, T.
Tetrahedron Lett. 2015, 56, 3830.

"Photoracemization of Blestriarene C and Its Analogs"
Natori, K.; Iwayama, T.; Yamabe, O.; Kitamoto, Y.; Ikeda, H.; Sakamoto, K.; Hattori, T.; Miyano, S.
Chirality (Special Issue for Symposium on Molecular Chirality 2014 and Molecular Chirality Asia 2014) 2015, 27, 479.

"1,3-Diiodocalix[4]arene: Synthesis by Ullmann-Type Iodination of 1,3-Bistriflate Ester of Calix[4]arene, Conformational Analysis, and Transformation into 1,3-Dicarboxy-, Diformyl-, and Dialkylcalix[4]arenes"
Tanaka, S.; Umetsu, T.; Nebuya, S.; Morohashi, N.; Hattori, T.
J. Org. Chem. 2015, 80, 1070.

"Effect of Solvent Polarity on Enantioselectivity in Candida Antarctica Lipase B Catalyzed Kinetic Resolution of Primary and Secondary Alcohols"
Kitamoto, Y.; Kuruma, Y.; Suzuki, K.; Hattori, T.
J. Org. Chem. 2015, 80, 521.

2014

"Regioselective synthesis of 1,2- and 1,3-diaminothiacalix[4]arenes via nucleophilic aromatic substitution and their X-ray structures"
Katagiri, H.; Tanaka, S.; Ohkubo, K.; Akahira, Y.; Morohashi, N.; Iki, N.; Hattori, T.; Miyano, S.
RSC Adv. 2014, 4, 9608.

"Sulfonyl-bridged oligo(benzoic acid)s: Synthesis, X-ray structures, and properties as metal extractants"
Morohashi, N.; Nagata, K.; Hayashi, T.; Hattori, T.
J. Inclusion Phenom. Macrocyclic Chem. 2014, 78, 161.

2013

"Unique inclusion behaviour of 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetraaminothiacalix[4]arene towards small organic molecules"
Morohashi, N.; Katagiri, H.; Shimazaki, T.; Kitamoto, Y.; Tanaka, S.; Kabuto, C.; Iki, N.; Hattori, T.; Miyano, S.
Supramol. Chem. 2013, 25, 812.

"Switching of the Diastereomer Deposited during the Crystallization of N-[(S)-1-Phenylethyl]-2'-carbamoyl-1,1'-binaphthalene-2-carboxylic Acid: Investigation of the Mechanism of Dielectrically Controlled Resolution"
Kitamoto, Y.; Suzuki, K.; Morohashi, N.; Sakai, K.; Hattori, T.
J. Org. Chem. 2013, 78, 597.

2012

"Selective Extraction of Heavy Rare-earth Metal Ions with a Novel Calix[4]arene-based Diphosphonic Acid"
Morohashi, N.; Hayashi, T.; Nakamura, Y.; Kobayashi, T.; Tanaka, S.; Hattori, T.
Chem. Lett. 2012, 41, 1520.

"Absorption of Chlorinated Hydrocarbons Dissolved in Water with Pellets Made of p-tert-Butylcalix[4]arene and Silica Gel"
Morohashi, N.; Shibata, O.; Hattori, T.
Chem. Lett. 2012, 41, 1412.

"Electrophilic Aromatic Substitution of Arenes with CO₂ Mediated by R₃SiB(C₆F₅)₄"
Konno, M.; Chiba, M.; Nemoto, K.; Hattori, T.
Chem. Lett. 2012, 41, 913.

"Direct Carboxylation of Thiophenes and Benzothiophenes with the Aid of EtAlCl₂"
Nemoto, K.; Onozawa, S.; Konno, M.; Morohashi, N.; Hattori, T.
Bull. Chem. Soc. Jpn. 2012, 85, 369.

"AlX₃/R₃SiXまたはR_nAlX_3-nを用いる二酸化炭素による芳香族化合物の直接カルボキシル化"
今野　惠；根本耕司；服部徹太郎
ケミカルエンジニアリング 2012, 57, 208.

2011

"Unique Inclusion Properties of Crystalline Powder p-tert-Butylthicacalix[4]arene toward Alcohols and Carboxylic Acids"
Morohashi, N.; Noji, S.; Nakayama, H.; Kudo, Y.; Tanaka, S.; Kabuto, C.; Hattori, T.
Org. Lett. 2011, 13, 3292.

"Synthesis of Mono- and 1,3-Diaminocalix[4]arenes via Ullmann-Type Amination and Amidation of 1,3-Bistriflate Esters of Calix[4]arenes"
Nakamura, Y.; Tanaka, S.; Serizawa, R.; Morohashi, N.; Hattori, T.
J. Org. Chem. 2011, 76, 2168.

"Synthesis of novel dihydroxydiphosphines and dihydroxydicarboxylic acids having a tetra(thio-1,3-phenylene-2-yl) backbone"
Akahira, Y.; Nagata, K.; Morohashi, N.; Hattori, T.
Supramol. Chem. 2011, 23, 144.

2010

"Direct Carboxylation of Arenes and Halobenzenes with CO₂ by the Combined Use of AlBr₃ and R₃SiCl"
Nemoto, K.; Yoshida, H.; Egusa, N.; Onozawa, S.; Morohashi, N.; Hattori, T.
J. Org. Chem. 2010, 75, 7855.

"誘電率制御分割法の可能性を探る"
北本雄一；服部徹太郎
化学工業 2010, 61, 840.

"芳香族化合物のカルボキシル化反応"
服部徹太郎
使える！有機合成反応241実践ガイド，丸岡啓二，野崎京子，石井康敬，大寺純蔵，富岡清編著，化学同人，2010, p. 50.

"カリックス[4]アレーン類のアミノ化反応"
服部徹太郎
使える！有機合成反応241実践ガイド，丸岡啓二，野崎京子，石井康敬，大寺純蔵，富岡清編著，化学同人，2010, p. 336.

2009

"Carboxylation of indoles and pyrroles with CO₂ in the presence of dialkylaluminum halides"
Nemoto, K.; Onozawa, S.; Egusa, N.; Morohashi, N.; Hattori, T.
Tetrahedron Lett. 2009, 50, 4512.

"Crystallization-based optical resolution of 1,1'-binaphthalene-2,2'-dicarboxylic acid via 1-phenylethylamides: Control by the molecular structure and dielectric property of solvent"
Kato, Y.; Kitamoto, Y.; Morohashi, N.; Kuruma, Y.; Oi, S.; Sakai, K.; Hattori, T.
Tetrahedron Lett. 2009, 50, 1998.

"溶媒の誘電率によるキラル識別の制御－誘電率制御分割法の原理と有用性"
北本雄一；服部徹太郎
化学 2009, 64(4), 68.

2008

"Sulfur-bridged Oligo(benzoic acid)s as a Novel Family of Metal Extractants"
Morohashi, N.; Nagata, K.; Tanaka, S.; Ohba, Y.; Hattori, T.
Chem. Lett. 2008, 37, 1228.

"α-アミノニトリルジアステレオマーの配座解析"
櫻井ルミ子；内田　朗；服部徹太郎；山浦政則
日本コンピュータ化学会論文誌 2008, 7, 177.

"Resolution of inherently chiral anti-O,O'-dialkylthiacalix[4]arenes and determination of their absolute stereochemistries"
Narumi, F.; Matsumura, N.; Sasagawa, N.; Natori, K.; Kajiwara T.; Hattori, T.
Tetrahedron: Asymmetry 2008, 19, 1470.

"Synthesis of Dinuclear Boron Complexes of Sulfinylcalix[4]arenes:  Syn/Anti Stereocontrol by the Arrangement of the Sulfinyl Functions"
Morohashi, N.; Kitahara, T.; Arima, T.; Tanaka, S.; Ohba, Y.; Hattori, T.
Org. Lett. 2008, 10, 2848.

"Synthesis of a Sulfur-bridged Diphosphine Ligand and Its Unique Complexation Properties toward Palladium(II) Ion"
Morohashi, N.; Akahira, Y.; Tanaka, S.; Nishiyama, K.; Kajiwara, T.; Hattori, T.
Chem. Lett. 2008, 37, 418.

2007

"Ullmann coupling reaction of 1,3-bistriflate esters of calix[4]arenes: facile syntheses of monoaminocalix[4]arenes and 4,4':6,6'-diepithiobis(phenoxathiine)"
Tanaka, S.; Serizawa, R.; Morohashi, N.; Hattori, T.
Tetrahedron Lett. 2007, 48, 7660.

"Conformational Behaviors of Tetra-O-methylsulfinylcalix[4]arenes--An Approach to Control the Conformation of Thiacalix[4]arenes by Oxidizing Sulfur Bridges"
Katagiri, H.; Hattori, T.; Morohashi, N.; Iki, N.; Miyano, S.
J. Org. Chem. 2007, 72, 8327.

"Intramolecular rearrangement of 1,3-bistriflate ester of thiacalix[4]arene to 1,2-counterpart: An efficient di-O-protection method for the stereoselective synthesis of anti-1,2-diethers"
Serizawa, R.; Tanaka, S.; Morohashi, N.; Narumi, F.; Hattori, T.
Tetrahedron Lett. 2007, 48, 6281.

"Synthesis and X-ray structures of iodothiacalix[4]arenes"
Tanaka, S.; Katagiri, H.; Morohashi, N.; Hattori, T.; Miyano, S.
Tetrahedron Lett. 2007, 48, 5293.

"Synthesis and binding studies of novel thiacalixpodands and bisthiacalixarenes having O,O''-dialkylated thiacalix[4]arene unit(s) of 1,3-alternate conformation"
Bhalla, V.; Babu, J. N.; Kumar, M.; Hattori, T.; Miyano, S.
Tetrahedron Lett. 2007, 48, 1581.

2006

"Thiacalixarenes"
Morohashi, N.; Narumi, F.; Iki, N.; Hattori, T.; Miyano, S.
Chem. Rev. 2006, 106, 5291.

"Beneficial effect of TMSCl in the Lewis acid-mediated carboxylation of aromatic compounds with carbon dioxide"
Nemoto, K.; Yoshida, H.; Suzuki, Y.; Morohashi, N.; Hattori, T.
Chem. Lett. 2006, 35, 820.

"Highly regioselective [2+2+2] cycloaddition of terminal alkynes catalyzed by titanium complexes of p-tert-butylthiacalix[4]arene"
Morohashi, N.; Yokomakura, K.; Hattori, T.; Miyano, S.
Tetrahedron Lett. 2006, 47, 1157.

2005

"Resolution of inherently chiral anti-O,O'-dialkylated calix[4]arenes and determination of their absolute stereochemistries by CD and X-ray methods"
Narumi, F.; Hattori, T.; Yamabuki, W.; Kabuto, C.; Kameyama, H.
Tetrahedron: Asymmetry 2005, 16, 793.

"Synthesis and binding studies of novel bisthiacalix[4]arenes with diimime linkages"
Bhalla, V.; Kumar, M.; Katagiri, H.; Hattori, T.; Miyano, S.
Tetrahedron Lett. 2005, 46, 121.

2004

"Racemic [1SR,2RS,(RS)]-N-cyano(phenyl)methyl-1-aminoindan-2-ol: crystal structure and reactivity towards thermal epimerization in the solid state"
Sakurai, R.; Itoh, O.; Uchida, A.; Hattori, T.; Miyano, S.; Yamaura, M.
Tetrahedron 2004, 60, 10553.

"Synthesis of an inherently chiral O,O'-bridged thiacalix[4]crowncarboxylic acid and its application to a chiral solvating agent"
Narumi, F.; Hattori, T.; Matsumura, N.; Onodera, T.; Katagiri, H.; Kabuto, C.; Kameyama, H.; Miyano, S.
Tetrahedron 2004, 60, 7827.

"Stereoselective synthesis of all stereoisomers of vicinal and distal bis(O-2-aminoethyl)-p-tert-butylthiacalix[4]arene"
Bhalla, V.; Kumar, M.; Hattori, T.; Miyano, S.
Tetrahedron 2004, 60, 5881.

"Epimerization of Diastereomeric α-Amino Nitriles to Single Stereoisomers in the Solid State"
Sakurai, R.; Suzuki, S.; Hashimoto, J.; Baba, M.; Itoh, O.; Uchida, A.; Hattori, T.; Miyano, S.; Yamaura, M.
Org. Lett. 2004, 6, 2241.

"Stereoselective dialkylation of the proximal hydroxy groups of calix- and thiacalix[4]arenes"
Narumi, F.; Hattori, T.; Morohashi, N.; Matsumura, N.; Yamabuki, W.; Kameyama, H.; Miyano, S.
Org. Biomol. Chem. 2004, 2, 890.

"Asymmetric synthesis of ternaphthalenes via an ester-mediated nucleophilic aromatic substitution reaction"
Hattori, T.; Iwato, H.; Natori, K.; Miyano, S.
Tetrahedron: Asymmetry 2004, 15, 881.

"Interconversion between syn and anti conformations of 1,3-bis(O-cyanomethyl)-p-tert-butylthiacalix[4]arene"
Bhalla, V.; Kumar, M.; Kabuto, C.; Hattori, T.; Miyano, S.
Chem. Lett. 2004, 33, 184.

2003

"Lewis acid-mediated carboxylation of aryl- and allylsilanes with carbon dioxide"
Hattori, T.; Suzuki, Y.; Miyano, S.
Chem. Lett. 2003, 32, 454.

"Synthesis of All Stereoisomers of Sulfinylcalix[4]arenes"
Morohashi, N.; Katagiri, H.; Iki, N.; Yamane, Y.; Kabuto, C.; Hattori, T.; Miyano, S.
J. Org. Chem. 2003, 68, 2324.

"Synthesis, Resolution, and Absolute Stereochemistry of (-)-Blestriarene C"
Hattori, T.; Shimazumi, Y.; Goto, H.; Yamabe, O.; Morohashi, N.; Kawai, W.; Miyano, S.
J. Org. Chem. 2003, 68, 2099.